AP®︎ Chemistry: Topic 2.1 Flashcards

Master key terms and definitions for Topic 2.1 of AP Chemistry – Types of Chemical Bonds to help you prep for quizzes and the AP exam.


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Term

Electronegativity

Definition

An atom's ability to attract shared electrons in a chemical bond.

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Electronegativity
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An atom's ability to attract shared electrons in a chemical bond.

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Electronegativity Trends
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Increases across a period and decreases down a group because of charge and distance effects.

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Coulomb's Law
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Attraction increases with larger charges and shorter distances between oppositely charged particles.

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Valence Electrons
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Outermost electrons that participate in bonding and determine many chemical properties.

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Nonpolar Covalent Bond
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Electrons are shared nearly equally between atoms with similar electronegativities.

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Polar Covalent Bond
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Electrons are shared unequally between atoms with different electronegativities.

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Partial Charges
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Delta positive and delta negative charges caused by unequal electron distribution in a bond.

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Bond Dipole
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A separation of charge in a bond caused by unequal electron sharing.

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Ionic Character and Bonding Continuum
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Polar bonds have some ionic character, so bonding ranges continuously from covalent to ionic.

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Ionic Bonding
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Electrostatic attraction between cations and anions, usually formed after electron transfer.

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Cation and Anion
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Cations are positively charged ions; anions are negatively charged ions.

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Crystal Lattice
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A repeating three-dimensional arrangement of ions in an ionic solid.

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Properties of Ionic Compounds
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Usually brittle, high-melting solids that conduct electricity when molten or dissolved.

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Properties of Metals
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Conductive, malleable, ductile, and lustrous because mobile electrons move through the solid.

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Bond Type Identification
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Metal plus nonmetal is usually ionic; two nonmetals are usually covalent; metals are metallic.

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Electronegativity Difference Guidelines
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About 0 to 0.4 is nonpolar covalent, 0.4 to 1.7 polar covalent, above 1.7 often ionic.

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Compound Properties vs Electronegativity
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Observed properties classify bonding more reliably than electronegativity difference alone.

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Carbon-Hydrogen Bond
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A bond treated as effectively nonpolar because the electronegativity difference is very small.

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Metallic Bonding
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Attraction between metal cations and mobile valence electrons spread throughout the solid.

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