AP®︎ Chemistry: Topic 9.8 Flashcards

Master key terms and definitions for Topic 9.8 of AP Chemistry – Galvanic (Voltaic) and Electrolytic Cells to help you prep for quizzes and the AP exam.


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Term

Electrochemistry

Definition

The study of redox reactions that convert chemical energy and electrical energy into each other.

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Electrochemistry
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The study of redox reactions that convert chemical energy and electrical energy into each other.

9.8.A
Electrochemical Cell
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A device in which separated half-reactions transfer electrons through a wire and ions through solution.

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Half-Reactions
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Separate oxidation and reduction equations that show electron loss and gain in a redox process.

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Standard Reduction Potentials
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Tabulated voltages for reduction half-reactions under standard conditions, used to calculate overall cell voltage.

9.8.A
Anode and Cathode
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Anode is where oxidation occurs; cathode is where reduction occurs in all electrochemical cells.

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Electron Flow in Electrochemical Cells
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Electrons move through the wire from the anode to the cathode.

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Half-Cell Solutions
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Solutions containing the ions involved in each electrode reaction, allowing charge transfer and reaction progress.

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Voltmeter / Current-Measuring Device
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An external device connected to the circuit to measure the cell's potential difference or current.

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Electrode Mass Changes
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The oxidation electrode loses mass, while the reduction electrode gains mass when solid metal is deposited.

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Gas Evolution at an Electrode
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Gas forms at an electrode when a half-reaction produces a gaseous product, often seen as bubbles.

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Galvanic vs. Electrolytic Cells
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Spontaneous cells generate electrical energy, while nonspontaneous cells require external electrical energy.

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Cell Potential Calculations
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Overall voltage equals cathode reduction potential minus anode reduction potential; reversing changes sign only.

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Salt Bridge
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A tube of inert ions that maintains neutrality by sending anions to the anode and cations to the cathode.

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Electrodes
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Conductive surfaces where redox occurs; some are inert and only provide electron-transfer surfaces.

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Current
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The flow of positive charge through a circuit, opposite the direction of electron flow.

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