AP®︎ Chemistry: Topic 9.4 Flashcards

Master key terms and definitions for Topic 9.4 of AP Chemistry – Thermodynamic and Kinetic Control to help you prep for quizzes and the AP exam.


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Term

Kinetic Control

Definition

A situation where reaction rate, often limited by high activation energy, prevents noticeable product formation.

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Kinetic Control
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A situation where reaction rate, often limited by high activation energy, prevents noticeable product formation.

9.4.A9.4.A.2
Thermodynamic Favorability and Reaction Rate
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A negative ΔG means a process is favorable, but it may still occur extremely slowly.

9.4.A9.4.A.1
Thermodynamic Control
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Reaction behavior determined mainly by the free-energy difference between reactants and products.

9.4.A
Thermodynamically Favored but Not at Equilibrium
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A system may have a favorable forward process yet remain far from equilibrium if rate is negligible.

9.4.A9.4.A.2
Catalyst and Kinetic Control
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A catalyst provides a lower-energy pathway, increasing rate without changing overall thermodynamic favorability.

9.4.A9.4.A.2
Diamond to Graphite Conversion
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A spontaneous carbon allotrope change with negative ΔG that occurs extremely slowly because of a large barrier.

9.4.A9.4.A.2
Hydrogen Peroxide Decomposition with Iodide Catalyst
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A usually slow favorable reaction that becomes measurable when iodide lowers the activation energy.

9.4.A9.4.A.2
Activation Energy and Kinetic Control
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A large activation-energy barrier can keep a thermodynamically favored reaction extremely slow.

9.4.A9.4.A.2