AP®︎ Chemistry: Topic 6.4 Flashcards

Master key terms and definitions for Topic 6.4 of AP Chemistry – Heat Capacity and Calorimetry to help you prep for quizzes and the AP exam.


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Term

Calorimetry

Definition

The measurement of heat transfer by tracking temperature changes in an insulated system.

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Calorimetry
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The measurement of heat transfer by tracking temperature changes in an insulated system.

6.4.A6.4.A.1
Heat Transfer Equation
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q = mcΔT, where heat equals mass times specific heat times temperature change.

6.4.A6.4.A.1
Specific Heat Capacity
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The heat required to raise 1 gram of a substance by 1 degree Celsius.

6.4.A6.4.A.5
Heat Capacity and Molar Heat Capacity
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Heat capacity is heat per degree for an object; molar heat capacity is heat per degree per mole.

6.4.A6.4.A.5
Temperature Change
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The difference between final and initial temperature, calculated as Tfinal minus Tinitial.

6.4.A
First Law of Thermodynamics
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Energy is conserved; it can be transferred or converted but not created or destroyed.

6.4.A6.4.A.2
Heat Lost Equals Heat Gained
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In an isolated calorimeter, energy released by one part equals energy absorbed by another.

6.4.A6.4.A.2
Sign of q in Heating and Cooling
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Positive q means heat is absorbed; negative q means heat is released.

6.4.A6.4.A.4
Specific Heat and Temperature Change Relationship
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For equal heat and mass, a larger specific heat gives a smaller temperature change.

6.4.A6.4.A.3
Solving for Unknown Specific Heat
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Set heat lost equal to heat gained, then solve q = mcΔT for c.

6.4.A6.4.A.1
Energy Changes in Chemical Systems
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Systems change energy through heating or cooling, phase changes, and chemical reactions.

6.4.A6.4.A.6
Coffee-Cup Calorimetry
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An insulated constant-pressure setup where measured heat equals the reaction’s enthalpy change.

6.4.A6.4.A.1
Dissolution Calorimetry
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A calorimetry method using solution temperature changes to identify heat flow during dissolving.

6.4.A6.4.A.7
Thermal Equilibrium
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The state reached when objects in contact stop changing temperature.

6.4.A